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Coumarin-based benzilmonohydrazone as a new proton-sensitive fluorescence dye: Synthesis and investigation of photophysical and acidochromic properties
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Coumarin-based chromogenic and fluorogenic dye 4 was designed and synthesized. The photophysical properties of 4 were determined in solvents with different polarities. Protonation affinity was determined by adding trifluoroacetic acid (TFA) to a dichloromethane solution of dye 4 utilizing the UV-Vis and fluorescence titration methods. The protonation region was investigated by using the 1H NMR method. Additionally, DFT and TDDFT studies were performed to support the structural and absorption spectral properties of 4.
Nội dung trích xuất từ tài liệu:
Coumarin-based benzilmonohydrazone as a new proton-sensitive fluorescence dye: Synthesis and investigation of photophysical and acidochromic properties
Nội dung trích xuất từ tài liệu:
Coumarin-based benzilmonohydrazone as a new proton-sensitive fluorescence dye: Synthesis and investigation of photophysical and acidochromic properties
Tìm kiếm theo từ khóa liên quan:
Journal of Chemistry Fluorescence dye Proton-sensitive dye Coumarin-based benzilmonohydrazone Fluorogenic dye sensors Environmental chemistryTài liệu liên quan:
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