Fabrication and electrochemical performance of La0.595V0.005Sr0.4MnO3−δ (LV05SM) cathode material for solid oxide fuel cells
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This study reports the effect of vanadium on the crystal structure and electrical and electrochemical properties of La0.6−x VxSr0.4MnO3−δ (x = 0.005–0.1) perovskite-based cathode materials in solid oxide fuel cells. Crystal structure, morphology, and porosity of prepared cathode materials are characterized by X-ray diffraction, X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy. Using XPS analysis it was established that the La3+ cation is exchanged by the V4+/5+ cation in the perovskite structure. This ion replacement improves the ionic conductivity and catalytic activity for oxygen reduction reaction in the perovskite structure, presumably due to the smaller size of the V4+/5+ cation than the La3+ ion.
Nội dung trích xuất từ tài liệu:
Fabrication and electrochemical performance of La0.595V0.005Sr0.4MnO3−δ (LV05SM) cathode material for solid oxide fuel cells
Nội dung trích xuất từ tài liệu:
Fabrication and electrochemical performance of La0.595V0.005Sr0.4MnO3−δ (LV05SM) cathode material for solid oxide fuel cells
Tìm kiếm theo từ khóa liên quan:
Journal of Chemistry Solid oxide fuel cells Oxygen reduction reaction Symmetric cells Electrochemical impedance spectroscopyTài liệu liên quan:
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