Danh mục

Peripherally 1,2-dinaphthyl ethanediol substituted phthalocyanine complexes: Synthesis, characterization, aggregation, and application in benzyl alcohol oxidation at room temperature

Số trang: 35      Loại file: pdf      Dung lượng: 2.15 MB      Lượt xem: 8      Lượt tải: 0    
Thư viện của tui

Xem trước 4 trang đầu tiên của tài liệu này:

Thông tin tài liệu:

In this study, the synthesis of a novel 1,2-dinaphthyl ethanediol substituted phthalonitrile (2) together with tetra-substituted zinc(II) phthalocyanine (Pc) (3) and cobalt(II) Pc (4) bearing 1,2-dinaphthyl ethanediol at peripheral positions was described. The aggregation behaviors of metallophthalocyanines 3 and 4 in solution were investigated by carrying out Beer–Lambert experiments at different concentrations. In addition, the catalytic activity of new cobalt(II) Pc 4 was investigated for benzyl alcohol oxidation. Benzyl alcohol was converted to benzaldehyde using cobalt(II) Pc 4 as a catalyst by a conversion of 99% with selectivity of 100% at room temperature in 1 h.
Nội dung trích xuất từ tài liệu:
Peripherally 1,2-dinaphthyl ethanediol substituted phthalocyanine complexes: Synthesis, characterization, aggregation, and application in benzyl alcohol oxidation at room temperature

Tài liệu được xem nhiều: