Báo cáo khoa học: The swinging movement of the distal histidine residue and the autoxidation reaction for midge larval hemoglobins
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Some insects have a globin exclusively in their fast-growinglarval stage. This is the case in the 4th-instar larva ofToku-nagayusurika akamusi, a common midge found in Japan.In the polymorphic hemoglobin comprised of 11 separablecomponents, hemoglobinVII (Ta-VIIHb) was of particularinterest. When its ferric met-form was exposed to pH 5.0from 7.2, the distal histidine was found to swing away fromtheE7 position.As a result, the iron(III) was converted froma hexacoordinate to a pentacoordinate form by a concom-itant loss of the axial water ligand. ...
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Báo cáo khoa học: The swinging movement of the distal histidine residue and the autoxidation reaction for midge larval hemoglobins
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Báo cáo khoa học: The swinging movement of the distal histidine residue and the autoxidation reaction for midge larval hemoglobins
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