Báo cáo Y học: Caged O2 Reaction of cytochrome bo3 oxidase with photochemically released dioxygen from a cobalt peroxo complex
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We developed the synthesis of the caged oxygen donor(l-peroxo)(l-hydroxo)bis[bis(bipyridyl)cobalt(III)] complex(HPBC) as nitrate salt,which has,compared with theperchlorate-form described previously [MacArthur,R.,Sucheta,A.,Chong,F.F. & Einarsdottir,O¨. (1995) Proc.Natl Acad. Sci. USA, 92,8105–8109],greatly enhancedsolubility. Now,the quantum efficiency of the photolyticalrelease of dioxygenwas determined tobe 0.4 per photon at alaser wavelength of 308 nm,which was used to observebiological reactions....
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Báo cáo Y học: Caged O2 Reaction of cytochrome bo3 oxidase with photochemically released dioxygen from a cobalt peroxo complex
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Báo cáo Y học: Caged O2 Reaction of cytochrome bo3 oxidase with photochemically released dioxygen from a cobalt peroxo complex
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